eprintid: 59572
rev_number: 50
eprint_status: archive
userid: 21521
dir: disk0/00/05/95/72
datestamp: 2026-04-10 08:07:45
lastmod: 2026-04-10 08:07:45
status_changed: 2026-04-10 08:07:45
type: thesis
metadata_visibility: show
contact_email: 3334210045@untirta.ac.id
creators_name: ARDIANSYAH, FARRAS
creators_id: 3334210045
contributors_type: http://www.loc.gov/loc.terms/relators/THS
contributors_type: http://www.loc.gov/loc.terms/relators/THS
contributors_name: JUNIARSIH, ANDINNIE
contributors_name: HILMAN, HILMAN
contributors_id: 198406032008122002
contributors_id: 20081294
title: Pengaruh Stirring Speed dan Solid Liquid Ratio pada Ekstraksi Timah dari Residu Dimethyl Oxide Black (Dob) dengan Metode Hydrochloric Acid Leaching
ispublished: pub
subjects: QD
subjects: TN
subjects: TP
divisions: Metalurgi
full_text_status: restricted
keywords: Dimethyl Oxide Black, Hydrochloric acid leaching, Ekstraksi timah, Stirring speed, Solid liquid ratio
abstract: Dimethyl oxide black (DOB) is a residue from the tin industry process that still contains approximately 60.2% Sn and has not yet been optimally utilized. This by product has the potential to be developed as a secondary tin resource to support resource efficiency and reduce industrial waste. This study aims to investigate the effect of stirring speed and solid liquid ratio on the percentage of Sn extraction during the leaching process using hydrochloric acid. DOB samples were leached using 4 M HCl solution at a temperature of 80°C for 120 minutes. The stirring speed variations applied were 300 RPM, 400 RPM, and 500 RPM, while the solid liquid ratio variations were 0.05 g/ml, 0.10 g/ml, and 0.15 g/ml. The Sn content in the solid DOB by product was analyzed using X-ray Fluorescence (XRF) and X-ray Diffraction (XRD), while the leachate was analyzed using XRF and Raman Spectroscopy. The results indicate that variations in stirring speed and solid liquid ratio do not linearly affect the percentage of Sn extraction. At a solid liquid ratio of 0.05 g/ml, changes in stirring speed have a relatively minor effect on Sn extraction due to minimal external diffusion resistance. Meanwhile, at medium and high solid liquid ratios, the percentage of Sn extraction is influenced by complex interactions between shear forces, particle suspension, and film diffusion resistance. The highest Sn extraction percentage was obtained at a solid liquid ratio of 0.15 g/ml, indicating that increasing the solid content can enhance leaching effectiveness up to a certain limit. These findings suggest the presence of an optimum stirring condition in the extraction process of Sn from DOB by products.
date: 2026
date_type: published
pages: 69
institution: Fakultas Teknik Universitas Sultan Ageng Tirtayasa
department: Teknik Metalurgi
thesis_type: sarjana
thesis_name: sarjana
referencetext: Arham, L. O. (2018). Studi Perolehan Kembali Timah dari Limbah Kerak Reaktor Pembuatan Organotin asal PT Timah Industri dengan Metode Pelindian Menggunakan Asam Sulfat dan Electrowinning. Bandung: Institut Teknologi Bandung.
Beckhoff, B., Kanngießer, B., Langhoff, N., Wedell, R., & Wolff, H. (2006). Handbook of Practical X-Ray Flourescence Analysis. Berlin: Springer.
Cotton, A., Wilkinson, G., Murillo, C., & Bochmann, M. (2007). Advanced Inorganic Chemistry. New York : Wiley.
Davies, A. G. (2004). Organotin Chemistry. London: Wiley-VCH.
Faraji, F., Alizadeh, A., Rashchi, F., & Mostouf, N. (2020). Kinetics of Leaching: a review. Reviews in Chemical Engineering, 38(2), 1-35.
Folarin, & Sadiku. (2011). Thermal stabilizers for poly(vinyl chloride): A review. International Journal of the Physical Sciences , 6(18), 4324-4330.
Ghosh, N., Roy, S., Bandyopadhyay, A., & Mondal, J. A. (2023). Vibrational Raman Spectroscopy of the Hydration Shell of Ions. Liquids, 3(1), 19-39.
Hao, J., Wang, X., Guo, F., & Wu, Y. (2022). Optimization, Kinetic Studies of Tin Leaching from Waste Printed Circuit Boards and Selective Tin Recovery from Its Pregnant Solution. Metals, 1-15.
Harper, C. (2000). Modern Plastic Handbook. New York : McGraw-Hill.
International Tin Association. (2024). ITA Study: Tin use in recovery cycle. Hertfordshire: International Tin Association.
Jha, M. K., Choubey, P. K., Jha, A. K., Kumari, A., Lee, J.-c., Kumar, V., & Jeong, J. (2012). Leaching studies for tin recovery from waste e-scrap. Waste Management, 1919-1925.
Kim, S., Lee, J., & Yoo, K. (2015). Leaching of tin from waste Pb-free solder in hydrochloric acid solution with stannic chloride. Hydrometallurgy, 143-147.
Leba, M. (2017). Ekstraksi dan Real Kromatografi. Yogyakarta: Deepublish.
Nakamoto, K. (2009). Infrared and Raman Spectra of Inorganic and Coordination Compounds. New Jersey: Wiley.
Oliveira, R. d., & Santelli, R. E. (2010). Occurrence and chemical speciation analysis of organotin compounds in the environment: A review. Talanta, 82(1), 9-24.
Omoniyi, K. I. (2023). Dissolution Kinetics of the Hydrometallurgical Extraction of Tin from a Nigerian Cassiterite Ore Obtained From Jibia Local Government Katsina State . Communication in Physical Sciences, 4(9), 510-520.
Orlando, A., Franceschini, F., Muscas, C., Rovere, M., & AlbertoTagliaferro. (2021). A Comprehensive Review on Raman Spectroscopy Applications. Chemosensors, 9(262), 1-28.
Oxford Instruments. (2001). Lab-X3500 Benchtop XRF Analyser: Operating Instructions. High Wycombe: Oxford Instruments.
PANalytical B.V. (2007). PANalytical X'Pert PRO X-ray Diffraction System User's Guide. Almelo: PANanalytical B.V.
Patrick, S. (2004). PVC Compounds and Processing. Rapra Technology Ltd, 15(1), 3-15.
Pearce, J. (2015). Tin Chemical Roadmap 2015. Hertfordshire: ITRI.
PT. Timah Tbk. (2023). Laporan Tahunan. Jakarta: PT. Timah Tbk.
Qin, J., Ning, S., Fujitab, T., Wei, Y., Zhang, S., & Lu, S. (2021). Leaching of indium and tin from waste LCD by a time-efficient method assisted planetary high energy ball milling. Waste Management, 193-201.
Sahrind, M. F., Bahtiar, S., Khairy, K. T., Widyawati, F., Yanuar, E., & Suhaimi, L. (2025). Pengaruh Persen Padatan dan Penggunaan Oksidator H2O2 Pada Perolehan Kembali Emas Dari Tailing Amalgamasi Menggunakan Metode Klorinasi Basah. HEXAGON (Jurnal Teknik dan Sains), 6(1), 58-65.
Salim, Z. (2016). Info Komoditi Timah. Jakarta: Kemendag RI.
Smith, E., & Geoffrey, D. (2005). Modern Raman Spectroscору A Practical Approach. West Sussex: Willey.
Smith, P. J. (1998). Chemistry of Tin 2nd Edition. Glasgow: Springer.
Sohn, H. Y., & Wadsworth, M. E. (1979). Rate Processes of Extractive Metallurgy. New York: Plenum Press.
Sundoyo, H., & Hamsal, M. (2013). Reformulation of Business Strategies. The Indonesian Journal of Business Administration, 2(16), 1985-1993.
Trager, M. (2014). VinylPlus Progress Report 2014. Brussels: Vinylplus.
Wijayanto, W. (2021). Jenis dan Manfaat Logam. Gresik: CV RIZKI AULIA.
Wongnaree, N., Patcharawit, T., Yingnakorn, T., & Khumkoa, S. (2024). Leaching Kinetics of Valuable Metals from Calcined Material of Spent Lithium-Ion Batteries. ACS Omega(9), 46822-46833.
Yang, D., Wu, Z., Ren, K., Dong, P., Zhang, D., Yang, B., & Liang, F. (2023). Recent Advances of The Thermodynamic Behavior of Tin Species in Aqueous Solution. Journal of Mining and Metallurgy, 1-15.
Yurniar, V., Asra, R., & Adriadi, A. (2024). Quality and Shelf Life of Dragon Fruit (Hylocereus costaricensis) with Edible Coating of Watermelon Albedo Pectin with Addition of Ginger Extract (Zingiber officinale). Biospecies, 17(1), 1-12.
citation:   ARDIANSYAH, FARRAS  (2026) Pengaruh Stirring Speed dan Solid Liquid Ratio pada Ekstraksi Timah dari Residu Dimethyl Oxide Black (Dob) dengan Metode Hydrochloric Acid Leaching.  S1 thesis, Fakultas Teknik Universitas Sultan Ageng Tirtayasa.   
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