eprintid: 58827 rev_number: 15 eprint_status: archive userid: 13276 dir: disk0/00/05/88/27 datestamp: 2026-02-27 01:41:46 lastmod: 2026-02-27 01:41:46 status_changed: 2026-02-27 01:41:46 type: thesis metadata_visibility: show contact_email: danangd218@gmail.com creators_name: Prasetyo, Danang Dwi creators_id: 3334200035 contributors_type: http://www.loc.gov/loc.terms/relators/THS contributors_type: http://www.loc.gov/loc.terms/relators/THS contributors_name: Trenggono, Adhitya contributors_name: Yustanti, Erlina contributors_id: 197804102003121001 contributors_id: 196803262002122001 corp_creators: UNIVERSITAS SULTAN AGENG TIRTAYASA corp_creators: FAKULTAS TEKNIK corp_creators: JURUSAN TEKNIK METALURGI title: PENGARUH RASIO GO/Sn DAN KONSENTRASI H2SO4/H3PO4 TERHADAP SINTESIS SnO2@rGO DARI LIMBAH GRAFIT ELEKTRODA EAF UNTUK APLIKASI BATERAI LITHIUM ispublished: pub subjects: TN divisions: Metalurgi full_text_status: restricted keywords: Anoda, Grafena Oksida, Metode Hummers, Nanomaterial, Timah Oksida abstract: Industri baterai lithium-ion mengalami pertumbuhan yang signifikan dalam beberapa tahun terakhir. Dalam konteks sistem penyimpanan energi, Lithium ion battery (LIB) adalah teknologi penyimpanan energi elektrokimia yang paling canggih, digunakan dalam berbagai aplikasi seperti perangkat seluler, otomotif, dan elektronik lainnya. Material anoda merupakan bagian penting dari baterai lithium, material anoda yang paling banyak dikomersialkan adalah grafit. Salah satu material yang dapat digunakan untuk aplikasi anoda pada baterai lithium-ion adalah timah oksida (SnO2). Penelitian ini bertujuan untuk membuat serbuk komposit SnO2@rGO yang dibuat dengan cara memanfaatkan limbah grafit elektroda EAF (Electric Arc Furnace). Kemudian dilakukan reaksi Hummers untuk menghasilkan serbuk Grafena Oksida (GO). Setelah serbuk GO didapatkan kemudian serbuk GO dengan berat 4, 5, dan 6 gram disintesis dengan serbuk timah dengan menggunakan H2SO4 dan H3PO4 sebagai pelarut dengan variasi konsentrasi 100%H2SO4, 50%H2SO4:50%H3PO4, dan 100%H3PO4. GO kemudian tereduksi menjadi rGO (reduced Graphene Oxide) dan timah akan teroksidasi menjadi timah oksida dan timah fosfat. Setelah itu serbuk komposit timah/rGO dilakukan pengujian SEM (Scanning Electron Microscopy), XRD (X-ray Diffraction), dan pengujian sifat elektrokimia. Pada analisis XRD menunjukkan identifikasi empat fasa senyawa pada serbuk yang dihasilkan yaitu SnO2, rGO, SnS, dan Tin (II) Pyrophosphate. Nilai Rs dan Rct dari pengujian EIS yang terbaik terdapat pada sampel Z dikarenakan nilai Rs dan Rct yang didapatkan terendah. date: 2026-01-15 date_type: published pages: 91 institution: FAKULTAS TEKNIK SULTAN AGENG TIRTAYASA department: TEKNIK METALURGI thesis_type: sarjana thesis_name: sarjana referencetext: DAFTAR PUSTAKA [1] H. Liu et al., “Sn-based anode materials for lithium-ion batteries: From mechanism to modification,” Mar. 01, 2024, Elsevier Ltd. doi: 10.1016/j.est.2023.109862. [2] M. T. 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